The cobalt hydroxide nitrate was obtained via urea hydrolysis, as described elsewhere. The clp regulation makes sure that the hazards presented by chemicals are clearly communicated to. Mixtures of metalnonmetal nitrates with alkyl esters may explode, owing to the formation of alkyl nitrates. We have tried to make it as accurate and useful as possible, but can take no responsibility for its use, misuse, or accuracy.
Cobaltii nitrate react with ammonium hydroxide to produce cobaltii hydroxide and ammonium nitrate. Cobalt nitrate is the inorganic compound with the formula co no 3 2. Use the product attributes below to configure the comparison table. Cobalt nitrate is generally immediately available in most volumes. Rapid heating of cobaltiinitrate hexahydrate causes melting formation of a hydrate melt and therefore side reactions in the hydrate melt by. Cobalt nitrate hexahydrate cas no 10141056 anhydrous. Investigated as a tumorigen and a reproductive effector. Thermogravimetric analysis tga studies of cobalt nitrate hexahydrate, cupric nitrate trihydrate, ferric. First aid measures always seek professional medical attention after first aid measures are provided. Shut off ignition sources and call fire department. The substance identity section is calculated from substance identification information from all echa databases. Gives off irritating or toxic fumes or gases in a fire.
Thermal decomposition of bulk cobalt nitrate hydrate proceeds in several not. The nitrate anion is a univalent 1 charge polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms formula. The hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. Cobaltous nitrate hexahydrate, cobaltous nitrate, nitric acid, cobalt ii salt cas number 10026229. The information in cameo chemicals comes from a variety of data sources. Webelements periodic table cobalt cobalt trinitrate. What is the formula of cobalt ii chloride hexahydrate. The crystal structure of cobalt nitrate dihydrate, cono32 2 h2o in. Temperature programme reduction tpr studies of cobalt phases in. Thermal decomposition tg of cobaltiinitrate hexahydrate in n 2 atmosphere showing the influence of sample loading and possible side reaction with leaving water encirclement. Cobalt nitrate is the inorganic cobaltii salt of nitric acid, often with various amounts of water. Abstract the thermal decomposition of cobalt, nickel, manganese, zinc, and.
Catalyst handbook, 2nd ed wolfe publishing ltd london, england, 1989. The very slow thermal decomposition of 1, presented in fig. It is created by the interaction of cobalt oxide, hydroxide or. Structure, properties, spectra, suppliers and links for. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. To elucidate the unusual quasiisothermal driving modus of the investigation method examplarily the time dependence on the mass loss and on the temperature, respectively, is shown. Thermal decomposition of metal nitrates in air and hydrogen. Cobalt ii nitrate hexahydrate, 99% catalog numbers. Thermal decomposition of d metal nitrates supported on. Record the exact mass of the cobaltii nitrate hexa hydrate in the data table and transfer it to a 100 ml beaker.
The sample was ground lightly mid way in the heating cycle and finally stored in a desiccator over anhydrous calcium sul fate. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of usehandling. Thermal decomposition of bulk cobalt nitrate hydrate proceeds in several not well separated stages fig. Cobaltii chloride is an inorganic compound of cobalt and chlorine, with the formula cocl 2. Thermodynamic properties of substances the solubility of. Simple method to synthesize functionalized carbon nanotubes. The base metal hydrate, cano324h2o, showed two successive. Decomposition of cobalt nitrate supported on al 2 o 3 leads to coal 2 o 4 spinel as the final product at the temperature 210 c fig. Cobaltii nitrate cobaltous nitrate cobaltous nitrate hexahydrate keep people away. Cobalt oxide catalysts were prepared from the nitrate by thermal decomposition of cobalt nitrate hexahydrate at 691 for 20 hr. It is a hydrate, a cobalt salt and an inorganic nitrate salt. Preparation of nanoco3o4 by direct thermal decomposition of. You can view more details on each measurement unit. It is a raw material for the preparation of cobalt pigments and hair dyes.
Product and company identification cobalt nitrate, 6hydrate synonymsgeneral names. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. Kinetics of the thermal decomposition of anhydrous cobalt. Sep 20, 2009 cobaltii chloride hexahydrate has a pink color. Cobalt nitrate, hexahydrate, crystal, reagent, acs is an inorganic cobalt salt of nitric acid. Cobalt dinitrate hexahydrate is a hydrate that is the hexahydrate form of cobalt dinitrate. In figure 3 are identified cobalt oxide residues at the end of the test tgadsc, and the percentages of weight loss in water, nitrogen oxides, to be corroborated from the calculations in hsc 5. Nitric acid cobalt salt hexahydrate company identification. Search results for cobalt nitrate hexahydrate at sigmaaldrich.
A chemical reaction of cobaltii nitrate with sodium. The most common form is the hexahydrate co no 3 2 6h 2 o, which is a redbrown deliquescent salt that is soluble in water and other polar solvents. Hexahydrate cobalt nitrate was supplied by vetec, while pamino benzoic acid was supplied by sigmaaldrich. Physical cobaltii sulfate is a red anhydrous, monohydrate or pink hexa, heptahydrate crystalline solid, soluble in water, with the hydrated form more soluble in. Also record the appearance of the crystals in the observations section below the data. You have selected the maximum number of product attributes 3 to compare. The oxidation number of cobalt in cobalt nitrate hexahydrate is 2. Cobalt nitrate cono 3 2 6h 2 o is a red crystalline compound with a melting point of 56 c. Based on the thermal decomposition studies of cobaltii nitrate hexahydrate 43, it is possible to propose the scheme of the crystal decomposition.
Cobaltii nitrate hexahydrate h12con2o12 chemspider. One reagent lane fair lawn, nj 07410 for information in north america, call. The most common form is the hexahydrate cono326h2o, which is a. Cobalt ii nitrate cobaltous nitrate cobaltous nitrate hexahydrate keep people away. It has been shown the ability of the sample controlled reaction temperature scrt method for both discriminate the kinetic law and calculate the activation energy of the reaction. Cobaltii nitrate hexahydrate for sale,price,buy cobalt.
It loses water on heating and changes to a blue colored compound. Based on the thermal decomposition studies of cobalt ii nitrate hexahydrate 43, it is possible to propose the scheme of the crystal decomposition. Cobalt nitrate is the inorganic compound with the formula cono32. This information was last updated on september 8, 2003. Used as a battery additive, in the manufacture of cobalt pigments and invisible inks, for. Material safety data sheet cobaltii nitrate hexahydrate. It is a sky blue crystalline solid the compound forms several hydrates cocl 2 n h 2 o, for n 1, 2, 6, and 9. Cobalt ii nitrate hexahydrate revision date 19jan2018 hazard class 5. Catalytic decomposition of sodium chlorate sciencedirect. Cobalt nitrate cco cautionary response information common synonyms solid red odorless sinks and mixes with water. Add to the flask with calcium or lead nitrate solution small parts of cobalt salt. The decomposition of metal nitrates in air has been systematically studied.
Standard thermodynamic properties of chemical substances continued molecular. Add to the flask suspended in water cobalt compound and then add small parts of hot ammonium nitrate solution with heating and stirring. It is often a red brownish color and a deliquescent salt that is water soluble. Nov 28, 2014 the final product of bulk cobalt nitrate decomposition is co 3 o 4, which was confirmed by xrd analysis not shown here and stays in agreement with results presented in the literature 22, 24. Jul 01, 2005 thermal decomposition tg of cobaltiinitrate hexahydrate in n 2 atmosphere showing the influence of sample loading and possible side reaction with leaving water encirclement. Hereafter, the catalyst prepared from cobalt carbonate will be referred to as catalyst i. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the molecular and structural formulas. Claims of the formation of tri and tetrahydrates have not been confirmed. Thermal decomposition of d metal nitrates supported on alumina. Products sold by phytotechnology laboratories are intended for plant research and laboratory use only. Rapid heating of cobaltiinitrate hexahydrate causes melting formation of a. These products are not to be used as human or animal therapeutics, cosmetics, agricultural or pesticidal products, food additives, or as household chemicals.
Calculate how many grams you need to prepare 50 ml of 0. Cobalt ii nitrate hexahydrate substance information. More about the price and coa of cobaltii nitrate hexahydrate,please visit our website, and contact us. Cobaltii nitrate hexahydrate, thermal decomposition, nanoco3o4, characterization, filterpaperderived carbon electrode, electrochemical water. Safety data sheet according to 29cfr19101200 and ghs rev. Convert moles cobaltii nitrate hexahydrate to grams. Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally. Cobalt ii nitrate hexahydrate substance information echa. John dallas donaldson, detmar beyersmann, cobalt and cobalt compounds in ullmanns.
Thermal studies of nickel, cobalt, iron and copper oxides and. Not combustible but enhances combustion of other substances. As well as the anhydrous compound co no 3 2, several hydrates of cobalt ii nitrate exist. This thermal decomposition is best described by a johnsonmehlavrami kinetic model with n 2 with an activation energy of nuclei growth which fall in the range 5259 kj mol. Cobalt and its compounds have been shown to cause cancer in laboratory animals. Cobalt nitrate is a highly water soluble crystalline cobalt source for uses compatible with nitrates and lower acidic ph. This material contains cobaltii nitrate anhydrous listed as cobalt compounds. The chart below shows the calculated isotope pattern for the formula cono 3 3 with the most intense ion set to 100%. Honeywell fluka cobaltii nitrate hexahydrate, honeywell. Search results for cobaltii nitrate hexahydrate at sigmaaldrich.
Physical cobalt ii sulfate is a red anhydrous, monohydrate or pink hexa, heptahydrate crystalline solid, soluble in water, with the hydrated form more soluble in. Request pdf thermal decomposition of cobalt nitrato compounds. Cobaltii nitrate hexahydrate, 99%, pure, acros organics. The hazard classification and labelling section shows the hazards of a substance based on the standardised system of statements and pictograms established under the clp classification labelling and packaging regulation. The thermal decomposition of cobalt, nickel, manganese, zinc, and. We assume you are converting between moles cobaltii nitrate hexahydrate and gram. A hydrate that is the hexahydrate form of cobalt dinitrate. How many ml of the solution from question 1 do you need to prepare 50 ml of a 0. As it is in detail described in the literature, the. The final product of bulk cobalt nitrate decomposition is co 3 o 4, which was confirmed by xrd analysis not shown here and stays in agreement with results presented in the literature 22, 24.
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